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showing 10 items of 681 documents
Mass Transport in Nanoporous Gold and Correlation with Surface Pores for EC 1 Mechanism: Case of Ascorbic Acid
2021
International audience; Entry for the Table of Contents Playing with the pores: Surface pores size in nanoporous gold modulates the electrode reactions pathways of ascorbic acid. The reaction is largely driven by diffusion when pores are smaller (nanometer). On the contrary, adsorption holds the key role when pores are bigger (micrometer), allowing permeation of molecules in the film volume.
A lap joint simulant laboratory test method of aluminium alloys
2015
A lap joint simulant cavity (LJSC) with a gap thickness of 200 μm has been developed to test corrosion of assembled coated aluminium alloys. The LJSC was instrumented with electrodes allowing simultaneous pH and potential measurements in 0.5 M NaCl solution. Assuming the outer part of the LJSC is electrochemically inactive (painted sheet) it was confirmed that in free corroding conditions the pH inside the LJSC tends more towards alkalinisation. On the opposite, if the outer part of the LJSC is electrochemically active (unpainted sheet) the pH inside the LJSC tends towards an acidic value.
Photoinduced mass transport in amorphous As‐S‐Se films
2012
Direct surface patterning due to photoinduced mass transport in amorphous As-S-Se films has been studied. Illumination of the films with two orthogonally (±45°) polarized beam interference pattern causes the formation of surface relief gratings on the films due to lateral mass transport regarding to light propagation direction. The obtained experimental results showed the dependence of photoinduced surface relief depth (Δh) on film thickness during holographic recording from film side as well as from glass substrate side. After constant exposure doses for the films with a thickness d 1 μm values of Δh do not depend significantly on the film thickness for recording from film side but decreas…
Photoinduced mass transfer in amorphous As 2 S 3 films
2011
The surface relief grating formation in amorphous As2S3 films strongly depends on the polarization state of recording beams. The surface relief grating formation efficiency of s-s and p-p recording beam combination can be essentially enhanced by additional illumination with orthogonal polarization. It is shown that the direction of mass transport on the film surface is determined by the direction of light electric vector (© 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
Mass transport problems obtained as limits of p-Laplacian type problems with spatial dependence
2014
Abstract. We consider the following problem: given a bounded convex domain Ω ⊂ ℝ N ${\Omega \subset \mathbb {R}^N}$ we consider the limit as p → ∞ of solutions to - div ( b p - p | D u | p - 2 D u ) = f + - f - ${- \operatorname{div} (b_{p}^{-p} |Du|^{p-2} Du)=f_+ - f_-}$ in Ω and b p - p | D u | p - 2 ∂ u ∂ η = 0 ${ b_{p}^{-p} |Du|^{p-2} \frac{\partial u}{\partial \eta }=0}$ on ∂ Ω ${\partial \Omega }$ . Under appropriate assumptions on the coefficients bp that in particular verify that lim p → ∞ b p = b ${ \lim _{p\rightarrow \infty } b_p = b }$ uniformly in Ω ¯ ${\overline{\Omega }}$ , we prove that there is a uniform limit of u p j ${u_{p_j}}$ (along a sequence p j → ∞ ${p_j \rightarrow…
Electrodialysis with asymmetrically profiled membranes: Influence of profiles geometry on desalination performance and limiting current phenomena
2021
Abstract Electrodialysis (ED) has recently gained much attention in the wide field of desalination and water treatment. However, energy consumption and capital costs may impair the process competitiveness. In this regard, limiting current density (LCD) and current efficiency (η) are key performance parameters for optimized ED systems. In this work, an experimental campaign was carried out characterizing the performance of ED stacks when adopting asymmetrically profiled membranes. Current–voltage curves were recorded under different operating conditions mimicking the operation of brackish water or seawater desalination units. Results showed that there was a preferable direction of the electr…
Mass Transport Analysis of the Enhanced Buffer Capacity of the Bicarbonate-CO2 Buffer in a Phase-Heterogenous System: Physiological and Pharmaceutica…
2018
The bicarbonate buffer capacity is usually considered in a phase-homogeneous system, at equilibrium, with no CO2 transfer between the liquid buffer phase and another phase. However, typically, an in vitro bicarbonate buffer-based system is a phase-heterogeneous system, as it entails continuously sparging (bubbling) the dissolution medium with CO2 in a gas mixture, at constant ratio, to maintain a constant partial pressure of CO2 (g) and CO2(aq) molarity at a prescribed value, with CO2 diffusing freely between the gas and the aqueous phases. The human gastrointestinal tract is also a phase-heterogeneous system, with CO2 diffusing across the mucosal membrane into the mesenteric arterial blood…
Characterization of the Altered Zone Around a Fracture in Palmottu Natural Analogue
1996
AbstractA drill core sample penetrating at a natural fracture has been analysed by helium gas techniques and by α-autoradiography. Porosity and diffusivity profiles away from the fracture have been determined and compared with structural profiles. Model calculations are used to determine the effects of sample size on the measured porosities and diffusivities.
The use of non-cavitating coupling fluids for intensifying sonoelectrochemical processes
2020
Abstract For the first time, we have investigated the beneficial effects of non-cavitating coupling fluids and their moderate overpressures in enhancing mass-transfer and acoustic energy transfer in a double cell micro-sonoreactor. Silicon and engine oils of different viscosities were used as non-cavitating coupling fluids. A formulated monoethylene glycol (FMG), which is a regular cooling fluid, was also used as reference. It was found that silicon oil yielded a maximum acoustic energy transfer (3.05 W/cm2) from the double jacketed cell to the inner cell volume, at 1 bar of coupling fluid overpressure which was 2.5 times higher than the regular FMG cooling fluid. It was also found that the…
The modeling of dissimilar welding of immiscible materials by using a phase field method
2013
A multiphysical model of high power beam welding of immiscible materials is developed to explain the influence of operational parameters and materials properties on resulting morphology by simultaneous solving of heat transfer, fluid flow and mass transfer problems. The introduction of phase field description of the interface motion between two immiscible liquids allows obtaining the cartography of melted zone in function of two key-parameters: the position of heat source relatively to joint line and the welding speed. Due to the short thermal cycle limiting mass transfer, high power beam welding techniques may result in very inhomogeneous melted zones. In this study, the interest is paid t…